A stable carbene as π-acceptor electrochemical reduction to the radical anion

Autor:	Gerhard Raabe, J. Henrique Teles, Ahmed Ghanimi, Dieter Enders, Hartmut B. Stegmann, Klaus Breuer, Jacques Simonet
Rok vydání:	1997
Předmět:	Reduction (complexity) chemistry.chemical_compound chemistry Ab initio quantum chemistry methods Organic Chemistry Drug Discovery Electrochemistry Photochemistry Biochemistry Carbene Acceptor Ion
Zdroj:	Tetrahedron Letters. 38:2833-2836
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(97)00493-0
Popis:	The electrochemical reduction of the carbene 1 reversibly yielded the corresponding radical anion 2 , which was characterized by ESR measurements. Ab initio calculations provided a better understanding of its structure and stability.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::98a6b95a8ead08dd1eab122584706e23 https://doi.org/10.1016/s0040-4039(97)00493-0 Zobrazit plný text záznamu Full Text from ScienceDirect