An efficient synthesis of 2-(1-(E)-alkenyl)phenylphosphonates via Suzuki reaction of aryl nonaflates with (E)-1-alkenylboronates

Autor:	Ba-Tian Chen, Pei-Jiang Chen, Ai-Yun Peng
Rok vydání:	2013
Předmět:	Pinacol Aryl Organic Chemistry Biochemistry Medicinal chemistry Catalysis Inorganic Chemistry Solvent chemistry.chemical_compound chemistry Suzuki reaction Heck reaction Environmental Chemistry Organic chemistry Physical and Theoretical Chemistry
Zdroj:	Journal of Fluorine Chemistry. 151:58-62
ISSN:	0022-1139
Popis:	An efficient and general Suzuki coupling reaction between 2-phosphonylaryl nonaflates and ( E )-1-alkenylboronic pinacol esters using Pd(OAc) 2 /PPh 3 as catalysts, K 2 CO 3 as base and DMF as solvent has been developed. This strategy allows for convenient synthesis of twelve 2-(1-( E )-alkenyl)phenylphosphonates in good to excellent yields, most of which are not readily available by the previously reported Heck reaction of the same aryl nonaflates and terminal alkenes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::98859f1f1289c4fd6bc9eefee0931fc9 https://doi.org/10.1016/j.jfluchem.2013.03.015 Zobrazit plný text záznamu Full Text from ScienceDirect