Oxidative coupling of 4,5,6-trichloroguaiacol with iron(III) hexacyanoferrate(III)

Autor:	Carl Axel Wachtmeister, Kristina Arnoldsson
Rok vydání:	1991
Předmět:	Hexacyanoferrate III Dimer Organic Chemistry Diol Photochemistry Biochemistry Chloride Medicinal chemistry Quinone chemistry.chemical_compound chemistry Reagent Yield (chemistry) Drug Discovery medicine Oxidative coupling of methane medicine.drug
Zdroj:	Tetrahedron Letters. 32:543-546
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)79492-5
Popis:	Iron(III) hexacyanoferrate(III) is shown to be a useful reagent in oxidative coupling of 4,5,6-trichloroguaiacol (4,5,6-TCG). Dimerisation proceeds via oxidative demethylation and loss of chloride to give an ortho -quinonoid dimer in high yield. The proposed structure 1 is based largely on mass-spectra of methyl derivatives of the corresponding diol.
Databáze:	OpenAIRE
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