Theory of Unimolecular Reactions

Autor: H. E. Avery
Rok vydání: 1974
Předmět:
Zdroj: Basic Reaction Kinetics and Mechanisms ISBN: 9780333153819
DOI: 10.1007/978-1-349-15520-0_6
Popis: In a unimolecular reaction a single reactant molecule isomerises or decomposes to give a product or products. In terms of reaction-rate theory, the transition state or activated complex has a configuration similar to the reactant so that the process can be represented by $$A \to {A^\ddag } \to products$$
Databáze: OpenAIRE