New structural type in the chemistry of bismuth(III) polynuclear halide complexes: Synthesis and crystal structure of (H3O)3(diquat)6{[BiBr5]}6[BiBr6] • 2H2O
| Autor: | Sergey A. Adonin, Vladimir P. Fedin, Igor D. Gorokh, Denis G. Samsonenko, Ilya V. Korolkov, Maxim N. Sokolov |
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| Rok vydání: | 2016 |
| Předmět: |
Structural type
010405 organic chemistry Materials Science (miscellaneous) Inorganic chemistry Halide chemistry.chemical_element Crystal structure 010402 general chemistry 01 natural sciences Diquat 0104 chemical sciences Bismuth Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry Zigzag Octahedron Bromide Physical and Theoretical Chemistry |
| Zdroj: | Russian Journal of Inorganic Chemistry. 61:958-963 |
| ISSN: | 1531-8613 0036-0236 |
| Popis: | Complex (H3O)3(diquat)6{[BiBr5]}6[BiBr6] • 2H2O (I) has been prepared by the reaction between [BiBr6]3– and diaqua(1,1'-diethylene-2,2'-bipyridynium dibromide) in 2 M HBr and has been characterized by X-ray diffraction. The anionic part of compound I is formed by coordination polymeric anions {[BiBr5]–} n built of {BiBr6} octahedral blocks, which are joined by the μ2-bridge bromide ligands into infinite zigzag chains. The resulting complex belongs to new structural type among bismuth halide complexes. |
| Databáze: | OpenAIRE |
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