A family of low-molecular-weight organogelators based on Nα,Nɛ-diacyl-l-lysine: effect of alkyl chains on their organogelation behaviour

Autor:	Mariko Yumoto, Hirofusa Shirai, Masahiro Suzuki, Kenji Hanabusa
Rok vydání:	2008
Předmět:	chemistry.chemical_classification Stereochemistry Hydrogen bond Organic Chemistry Lysine complex mixtures Biochemistry Acylation chemistry.chemical_compound chemistry Amide Drug Discovery bacteria Organic chemistry lipids (amino acids peptides and proteins) Alkyl
Zdroj:	Tetrahedron. 64:10395-10400
ISSN:	0040-4020
DOI:	10.1016/j.tet.2008.08.061
Popis:	A family of low-molecular-weight organogelators based on Nα,Nɛ-diacyl- l -lysine was synthesized by acylation of Nɛ-dodecyl- l -lysine with acyl chlorides through the one-pot synthetic procedure and their organogelation properties were examined. These compounds functioned as an organogelator; especially, l -lysine derivatives possessing the branched alkyl groups are a better organogelation property. The NMR and IR studies demonstrate that the organogelation occurred through hydrogen bonding interactions between the amide groups and between the carboxy groups.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9828a3fa07febf1088aaee907672f20e https://doi.org/10.1016/j.tet.2008.08.061 Zobrazit plný text záznamu Full Text from ScienceDirect