Dehydrofluorination with triethylamine-boron trifluoride adduct. New synthesis of perfluoromethacrylic acid derivatives and related compounds

Autor:	I. L. Knunyants, Yu. V. Zeifman, U. Utebaev, T.V. Lushnikova, Yo.G. Abduganiev, E. M. Rokhlin
Rok vydání:	1975
Předmět:	Inorganic Chemistry chemistry.chemical_compound chemistry Reagent Organic Chemistry Environmental Chemistry Organic chemistry Physical and Theoretical Chemistry Biochemistry Triethylamine Boron trifluoride Adduct
Zdroj:	Journal of Fluorine Chemistry. 6:227-240
ISSN:	0022-1139
DOI:	10.1016/s0022-1139(00)83002-x
Popis:	Adduct (C2H5)3N·BF3 has proved to be a suitable dehydrofluorinating reagent for preparing highly reactive fluoroolefines through dehydrofluorination of corresponding monohydro derivatives. Its advantage over other dehydrofluorinating agents are demonstrated by the synthesis of a number of perfluoromethacrylic acid derivatives.
Databáze:	OpenAIRE
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