Thermo-kinetic research method for faster reactions: modifier method of distorted thermoanalytical curve

Autor:	Fu-Bin Jiang, Jia-Qing Xie, Xiancheng Zeng, Xiao-Nan Chen, Yong Chen
Rok vydání:	1999
Předmět:	Aqueous solution Thermokinetics Chemistry Thermal Analytical chemistry Physical and Theoretical Chemistry Condensed Matter Physics Kinetic energy Instrumentation Analysis method Calorimeter Research method
Zdroj:	Thermochimica Acta. 332:97-102
ISSN:	0040-6031
DOI:	10.1016/s0040-6031(99)00092-1
Popis:	Due to the thermal delay of calorimeter, the measured thermoanalytical curve was distorted. A method to modify the distorted thermoanalytical curve into the real thermoanalytical curve from which the kinetic parameter can be obtained directly has been established in this paper. The theoretical equation for calorimeter, in which the delay of sensing has been considered, and the thermo-kinetic research method for faster reactions, namely the modifier method of distorted thermoanalytical curve, have been suggested. The thermo-kinetics of a few faster reaction systems has been studied with this method and the validity of the theory and method has been verified by the experimental results.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::97fac8f245b618c8d89521ef7b2fda2c https://doi.org/10.1016/s0040-6031(99)00092-1 Zobrazit plný text záznamu Full Text from ScienceDirect