DRIFTS and Optical Microscopic Study of the Solventless Reaction between (η5-C5H5)M(CO)3CH3 (M = Mo, W) and L (L = P(p-FC6H4)3, P(C6H5)3)

Autor:	Neil J. Coville, and Asheena Budhai, Muhammad D. Bala
Rok vydání:	2004
Předmět:	Inorganic Chemistry Optical microscope Chemistry law Phase (matter) Organic Chemistry Kinetics Analytical chemistry Physical and Theoretical Chemistry law.invention
Zdroj:	Organometallics. 23:2048-2052
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om0343869
Popis:	The reaction between solid (η5-C5H5)M(CO)3CH3 and solid phosphines is shown to occur in the melt phase (optical microscopy), and a DRIFTS study of the melt reveals a well-behaved reaction following pseudo-first-order kinetics.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::97f0f534e8befc790c267116bd971ee9 https://doi.org/10.1021/om0343869 Zobrazit plný text záznamu