Autor:	O. E. Edwards, R. J. Kolt
Rok vydání:	1987
Předmět:	Organic Chemistry General Chemistry Catalysis
Zdroj:	Canadian Journal of Chemistry. 65:595-612
ISSN:	1480-3291 0008-4042
Popis:	Transformation of 3,7,9,11-tetraoxygenated lanostane derivatives into 3,7,11-trioxygenated cucurbit-1(10)-enes and cucurbit-5(10)-enes has been achieved. Attempts to convert the latter in good yield into cucurbit-5-enes are documented. The steric and electronic factors influencing the course of dehydration, under Westphalen conditions, of 9α-hydroxylanostane derivatives are discussed. Unusual autooxidation and dehydrogenation promoted by rhodium trichloride and iron pentacarbonyl are described.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::97e836fc65a89f9bd8922f8c18d10828 https://doi.org/10.1139/v87-104 Zobrazit plný text záznamu