Preparation and structural properties of new series of mixed-anion compounds: rare earth fluorosulfides

Autor:	Alain Demourgues, H. Laronze, Pierre Gravereau, Alain Tressaud, P. Macaudière
Rok vydání:	2001
Předmět:	Series (mathematics) Organic Chemistry Relaxation (NMR) Stacking Mineralogy Biochemistry Ion Inorganic Chemistry Bond length chemistry.chemical_compound Crystallography chemistry Atomic electron transition Environmental Chemistry Diffuse reflection Physical and Theoretical Chemistry Fluoride
Zdroj:	Journal of Fluorine Chemistry. 107:215-221
ISSN:	0022-1139
DOI:	10.1016/s0022-1139(00)00361-4
Popis:	Rare earth fluorosulfides with the following compositions: LnSF and Ln 2 AF 4 S 2 have been prepared by solid state routes. These structures can be described as a stacking of fluoride-based slabs ([Ln 2 F 2 ] 4+ in LnSF and [Ln 2 AF 4 ] 4+ in Ln 2 AF 4 S 2 ) and double layers [S 2 ] 4− . The fluoride blocks are related to fluorite-type structure. The relative compactness of the fluoride blocks leads to a relaxation of the LnS bond lengths.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::97d6591265445b0a79f95d2e30aa0c60 https://doi.org/10.1016/s0022-1139(00)00361-4 Zobrazit plný text záznamu Full Text from ScienceDirect