High molecular poly-α-alkenylphosphonates and phosphonamides

Autor:	V.A. Byl'yev, T.A. Yagfarova, B.Ye. Ivanov, Ya. A. Levin, Ya.I. Khristoforova, I. P. Gozman, L.Kh. Gazizova
Rok vydání:	1974
Předmět:	chemistry.chemical_classification Chain propagation Intermolecular force General Engineering Polymer Solvent chemistry.chemical_compound Monomer chemistry Polymerization Reagent Polymer chemistry Organic chemistry Degradation (geology)
Zdroj:	Polymer Science U.S.S.R.. 16:81-89
ISSN:	0032-3950
DOI:	10.1016/0032-3950(74)90119-1
Popis:	Polymerization of esters and amides of vinyl- and isopropenylphosphonic acids under the action of Grignard reagents leads to polymers with high intrinsic viscosities. The effect of the monomer structure, temperature and nature of the solvent on the stages of chain propagation, transfer and reinitiation is discussed. The formation of intermolecular P-O-P bonds has an important effect on the thermomechanical properties and the behaviour, during thermooxidative degradation, of the polymers formed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::97d04c0484535fd1192dd8702c8bbc1c https://doi.org/10.1016/0032-3950(74)90119-1 Zobrazit plný text záznamu