Infrared spectroscopy study of cyclopentanol self-associations

Autor:	G Vandendunghen, A.-C Draye, J. J. Tondeur
Rok vydání:	1996
Předmět:	Infrared Self association Analytical chemistry Infrared spectroscopy Ether Toluene Atomic and Molecular Physics and Optics Analytical Chemistry chemistry.chemical_compound chemistry Cyclopentanol Physical chemistry Acetonitrile Instrumentation Spectroscopy Equilibrium constant
Zdroj:	Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 52:1757-1768
ISSN:	1386-1425
DOI:	10.1016/s0584-8539(96)01736-9
Popis:	The predominant self-associations of cyclopentanol were determined from infrared data in toluene at 25 and 55°C, and in di- n -butyl ether and acetonitrile at 25°C. These associations correspond to a monomer-dimer-tetramer model in acetonitrile and di- n -butyl ether, and to a monomer-dimer-hexamer model in toluene. The molar extinction coefficients of the non-associated hydroxylic functions were determined in order to calculate the concentrations of the associated species and the corresponding equilibrium constants.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::97a07e3089d7c57549ee13dd50c54b2c https://doi.org/10.1016/s0584-8539(96)01736-9 Zobrazit plný text záznamu Full Text from ScienceDirect