Mathematical Techniques in the Study of Coriolis Coupling in Tetrahedral XY4 Molecules

Autor:	J. Brunvoll, B. N. Cyvin, S. J. Cyvin
Rok vydání:	2010
Předmět:	Force constant Chemistry Analytical chemistry Tetrahedron Molecule General Chemistry Physics::Chemical Physics Molecular physics Coriolis coupling Atomic mass
Zdroj:	Bulletin des Sociétés Chimiques Belges. 73:120-126
ISSN:	0037-9646
Popis:	Relations between Coriolis coupling coefficients in tetrahedral XY4 molecules are evaluated, using the method of Cα and related matrices. It appears that the Coriolis coupling may be studied in terms of two independent Coriolis coefficients, e.g. ζ24 and ζ44. For these two quantities explicit equations are deduced, containing atomic masses, vibrational frequencies (in terms of λ values), and force constants of the molecule.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::978bdcd849303d74fdcf0fa9274c6002 https://doi.org/10.1002/bscb.19640730114 Zobrazit plný text záznamu