Kinetic Features of the Radical Polymerization of Methyl Methacrylate under Conditions of Nitroxide-Mediated Reversible Inhibition

Autor:	M. Yu. Zaremski, V. V. Odintsova
Rok vydání:	2021
Předmět:	Nitroxide mediated radical polymerization Polymers and Plastics Radical Kinetics Radical polymerization Disproportionation General Chemistry Photochemistry Methacrylate chemistry.chemical_compound chemistry Polymerization Materials Chemistry Methyl methacrylate
Zdroj:	Polymer Science, Series C. 63:11-28
ISSN:	1555-614X 1811-2382
Popis:	This review summarizes our and published data on the kinetics and mechanism of controlled radical polymerization of methacrylates mediated by nitroxide radicals. The reasons influencing the possibility or impossibility of the realization of radical polymerization of methyl methacrylate in the mode of reversible inhibition are analyzed. The main factors determining the specificity of the nitroxide-mediated polymerization of methacrylates are the interaction of nitroxides with growing radicals by the disproportionation mechanism, the Fischer hypereffect, a high rate of reinitiation, and an abnormally low rate of reversible termination.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::97793ccabe8f7e67dbd3e537f60c4b59 https://doi.org/10.1134/s1811238221010069 Zobrazit plný text záznamu Full text from SpringerLink