Palladium(II) complexes bearing di-(2-picolyl)amine functionalized chrysin fragments. An experimental and theoretical study
| Autor: | Julian Cruz-Borbolla, Jorge Lopez, J. Martín Torres-Valencia, José Manuel Vásquez-Pérez, Simplicio González-Montiel, Javier Martin-Torres, Alejandro Valdez Calderón, Diego Martínez-Otero |
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| Rok vydání: | 2017 |
| Předmět: |
010405 organic chemistry
Stereochemistry Chemical shift Organic Chemistry Cationic polymerization chemistry.chemical_element 010402 general chemistry 01 natural sciences 0104 chemical sciences Analytical Chemistry Inorganic Chemistry chemistry.chemical_compound chemistry Polymer chemistry Molecule Moiety Amine gas treating Chrysin Methylene Spectroscopy Palladium |
| Zdroj: | Journal of Molecular Structure. 1145:112-120 |
| ISSN: | 0022-2860 |
| DOI: | 10.1016/j.molstruc.2017.05.076 |
| Popis: | A new series of chrysin derivatives containing the di-(2-picolyl)amine (2a–d) moiety have been designed, synthesized, and treated with PdCl2·2CH3CN allowing the preparation of new cationic Palladium(II) complexes (3a–d). Solution-phase studies by 1H NMR spectroscopy of 3a–d revealed that the protons of the methylene groups of the di(2-picolyl)amine fragment are diasterotopic. GIAO/DFT studies were performed to predict the molecular structures of 3a–d by comparing the experimental and theoretical 1H-NMR chemical shifts. The molecular structure of 3c was determined by X-ray crystallographic analysis revealing that di-(2-picolyl)amine fragment is coordinated to the palladium center in a κ3-N,N,N-tridentate fashion in an overall square-planar geometry completed with a chloride atom. |
| Databáze: | OpenAIRE |
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