Preliminary Study on Blend Based Mixed Ion- Electron Conductor- (PVA: PVK): CH3COONH4: EC System

Autor:	Shanker Lal Agrawal, Rajendra Prasad Kumhar
Rok vydání:	2014
Předmět:	Arrhenius equation Materials science Composite number Conductivity Ion chemistry.chemical_compound symbols.namesake chemistry Chemical engineering symbols Ionic conductivity Polymer blend Composite material Ammonium acetate Order of magnitude
Zdroj:	International Journal of Materials Science and Applications. 3:129
ISSN:	2327-2635
DOI:	10.11648/j.ijmsa.20140304.12
Popis:	An attempt has been made in the present work to develop blend based mixed ion-electron conductor viz. PVA: PVK: CH3COONH4: EC system. Formation of polymer blend and composite has been evidenced during XRD and IR studies. Ionic conductivity of this system is seen to improve by an order of magnitude at room temperature with optimum at 1.27×10-3 S/cm for 0.4 mole ammonium acetate concentration. Ionic charge transport seems to dominate as reflected from I-t measurements. Temperature dependent conductivity shows that ionic conduction is controlled by combination of Arrhenius and VTF behavior. AC conductivity behavior is seen to be dictated by Jonscher Power law.
Databáze:	OpenAIRE
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