Oxidation of 2-mercaptobenzoxazole in aqueous solution: solid phase formation at glassy carbon electrodes

Autor: Gunther Wittstock, Andrea G Schaufuß
Rok vydání: 1999
Předmět:
Zdroj: Journal of Solid State Electrochemistry. 3:361-369
ISSN: 1433-0768
1432-8488
DOI: 10.1007/s100080050168
Popis: The redox reactions of 2-mercaptobenzoxazole (MBO) have been investigated by cyclic voltammetry at glassy carbon electrodes in aqueous solution. Four anodic and three cathodic processes could be identified. A more detailed analysis of the oxidation processes up to a potential of +0.6 V (SCE) and the corresponding reduction signals showed that the oxidation leads to bis(benzoxazolyl) disulfide (BBOD). Owing to its low solubility, the oxidation product remains at the electrode surface. This product has been identified by ex situ FTIR and XPS analysis. During the reduction of BBOD, mainly MBO is formed. The remarkable lower solubility of BBOD in aqueous solutions compared to MBO allows preparation of layers of BBOD in situ and to control the amount of deposited BBOD via the MBO solution concentration and electrolysis time. The peak potential and peak shape of the reduction signals change remarkably as the amount of BBOD increases from submonolayer coverage to coverages that correspond to multilayers. The behavior can be explained by assuming an electrochemical conversion of BBOD microcrystals, which are deposited on the electrode surface, if the amount of BBOD formed during the MBO oxidation exceeds one monolayer.
Databáze: OpenAIRE
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