ChemInform Abstract: A Convenient Two-Step Procedure for the Synthesis of Di- and Trisubstituted α-Nitroalkenes from Tertiary β-Nitro Alcohols

Autor:	J. C. Ferrand, Raphaël Schneider, Philippe Gérardin, Bernard Loubinoux
Rok vydání:	2010
Předmět:	Potassium methoxide Acetic anhydride chemistry.chemical_compound Elimination reaction chemistry Two step Nitro chemistry.chemical_element Lithium General Medicine Medicinal chemistry
Zdroj:	ChemInform. 28
ISSN:	0931-7597
DOI:	10.1002/chin.199709044
Popis:	Treatment of tertiary β-nitro alcohols I, obtained by addition of lithium α-lithionitronates to ketones, with acetic anhydride followed by 1 equivalent of potassium methoxide or t-butoxide, according to the nature of R2, gives α-nitroalkenes III in good yields.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9733f44bb1c82c4ae5631251133fdafc https://doi.org/10.1002/chin.199709044 Zobrazit plný text záznamu Plný text