ChemInform Abstract: A Simple Synthesis of (+)- and (-)-Alkaloid 241D and C-4 Epimers

Autor: Yves Troin, Pierre Calinaud, Jean-Louis Canet, Stephane Ciblat
Rok vydání: 2010
Předmět:
Zdroj: ChemInform. 31
ISSN: 1522-2667
0931-7597
Popis: An enantioselective preparation of both enantiomers of alkaloid 241D 1 and its C-4 epimer is reported. This simple and concise synthesis, seven steps from pent-3-en-2-one, involves a highly diastereoselective Mannich-type cyclisation as the key step.
Databáze: OpenAIRE