Interaction of sulfofluoride group in the organofluorine compounds with silver oxide and carbonate

Autor:	G. A. Emel’yanov, V. M. Rodin, D. M. Kostycheva, D. P. Blinov, A. N. Genkin, V. V. Berenblit
Rok vydání:	2011
Předmět:	chemistry.chemical_classification Carboxylic acid Inorganic chemistry General Chemistry Catalysis chemistry.chemical_compound Membrane chemistry Carbonate Organic chemistry Reactivity (chemistry) Fluoride Silver oxide Silver carbonate
Zdroj:	Russian Journal of General Chemistry. 81:783-784
ISSN:	1608-3350 1070-3632
DOI:	10.1134/s1070363211040323
Popis:	For the successful use of these compounds in the modern membrane, catalytic, and other advanced technologies synthetic methods are required, which allow a consecutive utilization of the reactivity of sulfofluoride and fluorocarbonyl functions. In particular, when solving the problem of obtaining silver 2,2-difluoro-2(fluorosulfonyl)acetate, the reaction of this acid with silver oxide (method a) was examined assuming that sulfofluoride group will not be affected. However, the reaction of equimolar amounts of the starting compounds affords a mixture of the salts of sulfonic and carboxylic acids. Nonetheless, the synthesis of silver 2,2-difluoro-2(fluorosulfonyl)acetate was successfully performed by using the silver carbonate and carboxylic acid fluoride instead of the silver oxide and carboxylic acid. DOI: 10.1134/S1070363211040323
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::971b3c30c46ce5a1a14ed713e410ff05 https://doi.org/10.1134/s1070363211040323 Zobrazit plný text záznamu Plný text ve formátu PDF