Synthesis and complexing properties of phosphorylated imines of 8-formyl-7-hydroxycoumarin

Autor:	Diana V. Aleksanyan, Zinaida S. Klemenkova, L. V. Gumileva, Yu. V. Nelyubina, N. E. Shepel, Oleg I. Artyushin, Andrei A. Vasil'ev, Vladimir A. Kozlov, G. K. Genkina
Rok vydání:	2014
Předmět:	Schiff base Chemistry Stereochemistry Ligand Aryl chemistry.chemical_element General Chemistry Medicinal chemistry Catalysis chemistry.chemical_compound Aniline Phenylboronic acid Luminescence Palladium
Zdroj:	Russian Chemical Bulletin. 63:2309-2316
ISSN:	1573-9171 1066-5285
Popis:	Condensation of o-(diphenylthiophosphoryl)aniline with 8-formyl-7-hydroxy-4-methylcoumarin yields the Schiff base capable of acting as a tridentate monoanionic ligand upon coordination with the ReI and PdII ions. The corresponding palladium complex shows high catalytic activity in the Suzuki cross-couplings of aryl bromides with phenylboronic acid. The analogous P(O)-substituted ligand was not isolated in the pure form; however, using template-assisted method, its κ3-O,N,O-zinc complex was synthesized; this complex is luminescent in the MeCN solution at 20 ℃.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::970546ae5bd464225642de93962e2f3c https://doi.org/10.1007/s11172-014-0740-2 Zobrazit plný text záznamu Full text from SpringerLink