Ionic Processes in γ‐Irradiated Organic Solids: Positive‐Hole Migration in 3‐Methylpentane

Autor:	William H. Hamill, James B. Gallivan
Rok vydání:	1966
Předmět:	Biphenyl Absorption spectroscopy Diffusion Analytical chemistry General Physics and Astronomy Ionic bonding Radiation chemistry Photochemistry Ion chemistry.chemical_compound chemistry Physical and Theoretical Chemistry Absorption (chemistry) Benzene
Zdroj:	The Journal of Chemical Physics. 44:2378-2388
ISSN:	1089-7690 0021-9606
DOI:	10.1063/1.1727052
Popis:	The yields of positive and negative species trapped in γ‐irradiated organic glasses at −196° have been measured as a function of glass composition. Increased yields of solvent‐trapped electrons (e−) and biphenyl anions (φ2−), as well as decreased yields of various solute cations (A+), were noted when additives capable of undergoing charge‐transfer or proton‐transfer reactions were present in small amounts (
Databáze:	OpenAIRE
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