Kinetics of the reduction of orthorhombic and tetragonal lead oxides to lead with hydrogen

Autor:	Yu. A. Teplyakov, I. I. Ivanov, V. V. Ul’yanov, V. M. Shelemet’ev
Rok vydání:	2015
Předmět:	Hydrogen Oxide chemistry.chemical_element General Chemistry Activation energy Catalysis Computer Science Applications Tetragonal crystal system chemistry.chemical_compound Crystallography chemistry Modeling and Simulation Orthorhombic crystal system Reactivity (chemistry) Lead oxide
Zdroj:	Kinetics and Catalysis. 56:304-307
ISSN:	1608-3210 0023-1584
DOI:	10.1134/s0023158415030076
Popis:	The kinetics of the reduction of orthorhombic and tetragonal lead oxides to lead with hydrogen has been investigated in the temperature range from 450 to 525°C. The degree of reduction of lead in the orthorhombic oxide as a function of the reaction time is described by the Erofeev equation in which the exponent n is unity. No significant difference in reactivity toward hydrogen between orthorhombic and tetragonal lead oxides has been revealed. The activation energy of the lead oxide reduction reaction is 85.8 ± 8.3 kJ/mol for the orthorhombic phase and 93.1 ± 5.0 kJ/mol for the tetragonal phase, so these values are equal within the activation energy determination error.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::96ddb14af5665f92574381c5bb6d6406 https://doi.org/10.1134/s0023158415030076 Zobrazit plný text záznamu Plný text ve formátu PDF