Iron and Copper Salts in the Synthesis of Benzo[b]furans

Autor:	Maria Piedrafita, Julien Bonnamour, Carsten Bolm
Rok vydání:	2010
Předmět:	chemistry.chemical_compound chemistry Aryl Intramolecular force medicine Organic chemistry chemistry.chemical_element General Chemistry Medicinal chemistry Copper Chloride Catalysis medicine.drug
Zdroj:	Advanced Synthesis & Catalysis. 352:1577-1581
ISSN:	1615-4169 1615-4150
DOI:	10.1002/adsc.201000269
Popis:	Intramolecular C-O bond forming reactions of aryl 2-bromobenzyl ketones lead to benzo[b]furans. The cyclizations can be catalyzed by 10 mol% of iron trichloride (of 98% or of 99.995% purity) or sub-mol% quantities of copper(II) chloride (of 99.995% purity).
Databáze:	OpenAIRE
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