The use of inverse vulcanised polysulfide as an intelligent interfacial modifier in rubber/carbon black composites

Autor:	Aijia Wang, Zhenghai Tang, Baochun Guo, Shifeng Fang, Siwu Wu, Hui Zeng, Dong Wang
Rok vydání:	2021
Předmět:	Materials science Radical chemistry.chemical_element General Chemistry Carbon black Sulfur Styrene chemistry.chemical_compound chemistry Natural rubber visual_art Copolymer visual_art.visual_art_medium General Materials Science Composite material Dispersion (chemistry) Polysulfide
Zdroj:	Carbon. 184:409-417
ISSN:	0008-6223
Popis:	We reported the use of an inverse vulcanised polysulfide (SP) as an intelligent interfacial modifier in the NR/CB composites to remarkably decrease the hysteresis loss by enhancing the interfacial adhesion and improving CB dispersion. Specifically, SP synthesized by the bulk copolymerization of sulfur and styrene was grafted onto CB surface by trapping the sulfur radicals generated from SP, and the grafted polysulfides can participate in the crosslinking reaction with NR, which greatly improves CB dispersion and strengthens interfacial adhesion in the composites. As a consequence, the rolling resistance and heat build-up of the modified composites are remarkably decreased, showing great advantages in tire application in term of reducing fuel consumption and extending service life.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::96c8ccbe49a642cbe339596c5a5bbec9 https://doi.org/10.1016/j.carbon.2021.08.053 Zobrazit plný text záznamu Full Text from ScienceDirect