The Mechanism of Aminations of Halobenzenes1

Autor:	L. A. Carlsmith, John D. Roberts, Dorothy A. Semenow, Howard E. Simmons
Rok vydání:	1956
Předmět:	inorganic chemicals Aryl Halide General Chemistry Hydrogen atom Photochemistry Biochemistry Aryne Catalysis Metal chemistry.chemical_compound Colloid and Surface Chemistry chemistry visual_art Halogen Atom visual_art.visual_art_medium
Zdroj:	Journal of the American Chemical Society. 78:601-611
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja01584a024
Popis:	An elimination-addition mechanism, probably involving a "benzyne" intermediate, has been established for the rearrangements which often occur in the conversion of non-activated aryl halides to arylamines with metallic amides. The evidence for the "benzyne" intermediate was obtained through ^(14)C-tracer studies of rearrangements with halobenzenes and experiments designed to determine the role of the hydrogen atom located ortho to the displaced halogen atom.
Databáze:	OpenAIRE
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