Carboxamido carbonyl complexes of manganese(I)

Autor:	Robert J. Angelici, D.L. Denton
Rok vydání:	1968
Předmět:	Primary (chemistry) Infrared Inorganic chemistry chemistry.chemical_element Manganese Medicinal chemistry Ion Inorganic Chemistry chemistry Group (periodic table) Materials Chemistry Mass spectrum Amine gas treating Physical and Theoretical Chemistry
Zdroj:	Inorganica Chimica Acta. 2:3-7
ISSN:	0020-1693
Popis:	Mn(CO)5Br reacts with primary aliphatic amines, RNH2, to form carboxamido complexes, Mn(CO)4(CONHR)(NH2R): Mn(CO)5Br + 3RNH2→Mn(CO)4(CONHR)(NH2R + RNH3+Br−. Their reaction with HCl removes the −NHR group from the carboxamido group according to the equation: Mn(CO)4(CONHR)(NH2R) + 2HCl→[Mn(CO)5(NH2R)]+ Cl− + RNH3+Cl−. The [Mn(CO)5(NH2R)]+ ions react instantaneously with amine, RNH2, to regenerate the carboxamido complex, Mn(CO)4(CONHR)(NH2R). Infrared, nmr, and mass spectra of the new compounds are discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9688048b8d42b96365cee347754a5d3a https://doi.org/10.1016/s0020-1693(00)86982-0 Zobrazit plný text záznamu