Spectral study of ability of ferrocenylphosphines and ferrocenylphosphine oxides to form hydrogen bonds

Autor:	D. N. Kravtsov, Elena S. Shubina, V. D. Vil'chevskaya, V. S. Tolkunova, L. M. Épshtein, A. I. Krylova
Rok vydání:	1987
Předmět:	chemistry.chemical_compound chemistry Hydrogen bond Group (periodic table) Phosphorus atom Phenol General Chemistry Hyperconjugation Photochemistry Medicinal chemistry Phosphine
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 36:522-525
ISSN:	1573-9171 0568-5230
Popis:	1. Spectral and thermodynamic characteristics of H-complexes of phenol with phenyl- and ferrocenylphosphines and the corresponding phosphine oxides were determined. 2. The strength of the H-bonds increases upon replacement of the phenyl groups by ferrocenyl groups in the series: Ph3 < FcPh2 < Fc2Ph < Fc3. 3. The proton-acceptor ability of the ferrocenyl-substituted phosphines and phosphine oxides was found to be greater than in the case of the corresponding trialkyl-substituted derivatives. 4. The anomalously high donor properties of the Fc substituents are tentatively explained as hyperconjugation of the π-orbitals of rings with σ-bonds of phosphorus atom and the phosphoryl group.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::96877810c5d620786c48166956477c54 https://doi.org/10.1007/bf00955828 Zobrazit plný text záznamu Full text from SpringerLink