Structural studies on LixTiS2
| Autor: | A.H. Thompson, C.R. Symon |
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| Rok vydání: | 1981 |
| Předmět: | |
| Zdroj: | Solid State Ionics. :175-179 |
| ISSN: | 0167-2738 |
| DOI: | 10.1016/0167-2738(81)90078-3 |
| Popis: | Precise studies of the lattice parameters as a function of composition in LixTiS2 TiS2 provide conclusive evidence that a single-phase product exists for all x values. The data indicate that the TiS2 lattice expands on intercalation with Li because of charge transfer from the Li+ to TiS2- and not because of a propping of the layer by the Li+. Trends in the lattice parameters and the thermoelectric power suggests that there is a change in the composition-dependent electron transfer near x= 1 3 . For x 1 3 a rigid band model describes the electron donation. These results are consistent with recent band structure calculations. |
| Databáze: | OpenAIRE |
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