THE ELUSIVE C60S: THREE ATTEMPTED SYNTHESES
| Autor: | R. Bruce Weisman, Franco Cataldo, Sergei M. Bachilo, Dieter Heymann, Terry Marriott |
|---|---|
| Rok vydání: | 2002 |
| Předmět: |
chemistry.chemical_classification
Desorption ionization Fullerene Sulfide Organic Chemistry Photodissociation chemistry.chemical_element Photochemistry Mass spectrometry Sulfur Atomic and Molecular Physics and Optics Ion chemistry General Materials Science Compounds of carbon Physical and Theoretical Chemistry |
| Zdroj: | Fullerenes, Nanotubes and Carbon Nanostructures. 10:37-47 |
| ISSN: | 1536-4046 1536-383X |
| DOI: | 10.1081/fst-120002928 |
| Popis: | Results of semiempirical energy calculations suggested that a [6,6]-closed C60S fullerene sulfide might be stable. Attempts were therefore undertaken to synthesize the compound by UV photolysis of C60 in CS2 and by the heating of mixtures of C60 and S8 to 325 and 400°C. Any sulfide, if formed, was present in undetectably small quantities. However, [12C60 34S]− ions were observed when a mixture of solid C60 and elemental sulfur was analyzed by Laser Desorption Ionization Time-of-Flight mass spectrometry. |
| Databáze: | OpenAIRE |
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