PERFLUOROPIPERIDINE: ENTROPY, HEAT OF FORMATION, AND VAPOR PRESSURE; N-F BOND ENERGY; AND SOLID-STATE TRANSITIONS1,2

Autor:	S. S. Todd, J. P. Dawson, J. L. Lacina, J. F. Messerly, Donald W. Scott, J. P. McCullough, W. D. Good
Rok vydání:	1963
Předmět:	Vapor pressure Chemistry Transition temperature Binding energy Vaporization Inorganic chemistry Enthalpy General Engineering Thermodynamics Physical and Theoretical Chemistry Bond energy Heat capacity Standard enthalpy of formation
Zdroj:	The Journal of Physical Chemistry. 67:1306-1311
ISSN:	1541-5740 0022-3654
DOI:	10.1021/j100800a036
Popis:	Measurements were made of the thermodynamic properties of perfluoropiperidine, C/sub 5/F/sub 11/N. The experimental studies provided the following information: values of heat capacity for the solid above 12/sup 0/K and the liquid below 320/sup 0/K; temperature of two transitions in the solid state; triple-point temperature; heats of transition, fusion, and vaporization; vapor pressure (302 to 355/sup 0/K); and the standard heats of combustion and formation at 298.15/sup 0/K. A value for the N--F thermochemical bond energy was calculated from the results.
Databáze:	OpenAIRE
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