Structural studies of spiroarsoranes derived from 2-aminophenols

Autor:	Alejandro Alvarez, Francisco Pérez-García, Antonio R. Tapia-Benavides, Hugo Tlahuext, Margarita Tlahuextl
Rok vydání:	2006
Předmět:	Chemistry Computational chemistry Infrared X-ray Solid-state Physical chemistry Infrared spectroscopy Physical and Theoretical Chemistry Condensed Matter Physics Natural bond orbital
Zdroj:	Structural Chemistry. 17:359-366
ISSN:	1572-9001 1040-0400
Popis:	This paper describes the structural studies of 2-phenyl-9,9′-dimethyl-2,2′-spirobis(1,3,2-λ5-benzoxazarsoline) 5, 2-phenyl-8,8′-dimethyl-2,2′-spirobis(1,3,2-λ5-benzoxazarsoline) 6 by 1H,13C,15N NMR in [2H6]DMSO and CDCl3. The solid state studies were made by X-ray experiments. Infrared spectroscopy was obtained in CDCl3 and the vibrational signals were assigned using DFT calculations. The nature of the As–N, As–C and As–O bonds in these compounds was established by NBO studies.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::96623c5d33d656f495fb0ecd79435dde https://doi.org/10.1007/s11224-006-9035-z Zobrazit plný text záznamu Full text from SpringerLink