Ring Size-Selective Ring-Closing Olefin Metathesis: Taking Advantage of the Deleterious Effect of Ethylene Gas

Autor:	Kazuhiro Yoshida, Hidetoshi Takahashi, Akira Yanagisawa, Yuto Kano
Rok vydání:	2011
Předmět:	Ring size Olefin fiber chemistry.chemical_compound Ethylene Chemistry Organic Chemistry Ring-opening metathesis polymerisation Homogeneous catalysis Chemoselectivity Ring (chemistry) Photochemistry Metathesis Catalysis
Zdroj:	Advanced Synthesis & Catalysis. 353:1229-1233
ISSN:	1615-4150
DOI:	10.1002/adsc.201000944
Popis:	The deleterious effect of ethylene gas on the ring-closing olefin metathesis (RCM) for the formation of 5- to 8-membered rings was investigated. Significant rate differences caused by ethylene gas were observed among the different ring-size formation reactions. Nevertheless, the rate differences can be advantageously utilized for chemoselective RCM.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::965ef9643ce9a1de355e6eff7853b105 https://doi.org/10.1002/adsc.201000944 Zobrazit plný text záznamu Plný text