The syntheses and structures of lithium phosphinimide and phosphinimine complexes

Autor:	Silke Courtenay, Douglas W. Stephan, Pingrong Wei
Rok vydání:	2003
Předmět:	Steric effects Crystallography chemistry.chemical_compound Chemistry Organic Chemistry chemistry.chemical_element Lithium General Chemistry Catalysis Derivative (chemistry)
Zdroj:	Canadian Journal of Chemistry. 81:1471-1476
ISSN:	1480-3291 0008-4042
DOI:	10.1139/v03-162
Popis:	The preparation and structures of [Li(µ-NPt-Bu3)]4 1, [Li(µ-Cl)(HNPt-Bu3)]4 2, and [Li(µ-Cl)(HNPPh3)]4 3 are described. The structure of 1 stands in contrast to that of the only other known Li-phosphinimide derivative, [Li(µ-NPPh3)]6. The impact of the steric bulk on the aggregation and the geometries of the Li4N4 and Li4Cl4 cores are considered and discussed.Key words: lithium compounds, phosphinimine, phosphinimide, P-N ligands.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9651e096a37d4b9b0063ffc81e7ecac7 https://doi.org/10.1139/v03-162 Zobrazit plný text záznamu Plný text ve formátu PDF