A new sensor for copper(II) ion based on carboxyl acid groups substituted polyfluoreneethynylene
| Autor: | Junping Du, Shijie Ren, Qiang Fang, Jing Sun, Hongliang Zhong, Erjian Xu, Danli Zeng, Jian‐Gong Cheng |
|---|---|
| Rok vydání: | 2008 |
| Předmět: |
chemistry.chemical_classification
Polymers and Plastics General Chemical Engineering Carboxylic acid Sonogashira coupling General Chemistry Polymer Conjugated system Biochemistry Polyelectrolyte chemistry Polymer chemistry Materials Chemistry Side chain Environmental Chemistry Selectivity Repeat unit |
| Zdroj: | Reactive and Functional Polymers. 68:1715-1721 |
| ISSN: | 1381-5148 |
| Popis: | A new conjugated polymer based on polyfluoreneethynylene has been synthesized by Sonogashira coupling reaction. Each repeat unit of the polymer contains two carboxylic acid groups which can selectively incorporate with Cu 2+ in methanol. The sensitivity was extremely high through an efficient fluorescence quenching process amplified by the polymer aggregation mechanism. Such polymer will be a good candidate of the new fluorescence sensors for Cu 2+ with good selectivity and high sensitivity. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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