ChemInform Abstract: An Air-Stable Palladium/N-Heterocyclic Carbene Complex and Its Reactivity in Aryl Amination

Autor:	Rebecca M. Kissling, Steven P. Nolan, Mihai S. Viciu, Edwin D. Stevens
Rok vydání:	2010
Předmět:	chemistry.chemical_compound chemistry Reagent Aryl chemistry.chemical_element Amine gas treating Reactivity (chemistry) General Medicine Carbene Medicinal chemistry Amination Catalysis Palladium
Zdroj:	ChemInform. 33
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200244070
Popis:	The synthesis and characterization of [Pd(IPr)Cl2]2 (1), an air- and moisture-stable complex, is reported. The utilization of 1 as a catalyst for amination of aryl chlorides and bromides with a variety of amine coupling partners under mild conditions is described. The amination reactions with 1 show a remarkable insensitivity to oxygen and water, and thus the amination reactions could be performed in air on the benchtop with undried reagent grade solvents and substrates with small effects on reaction times and conversions.
Databáze:	OpenAIRE
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