Coordination compounds of CuCl2 with 1-(N-heterylmethyl)silatranes

Autor: E. N. Timofeeva, Vera V. Belyaeva, Elena F. Belogolova, Yu. I. Bolgova, Olga M. Trofimova
Rok vydání: 2016
Předmět:
Zdroj: Russian Chemical Bulletin. 65:1039-1046
ISSN: 1573-9171
1066-5285
Popis: Reactions of CuCl2 with 1-(N-indolylmethyl)and 1-(N-carbazolylmethyl)silatranes (L) afforded new complexes CuCl2•L. Quantum chemical calculations of these complexes and a CuII complex with 1-(N-pyrrolylmethyl)silatrane showed that the Cu atom is coordinated to both the equatorial O atom of the silatranyl group and the π-system of the ligandś heterocycle.
Databáze: OpenAIRE