Coordination compounds of CuCl2 with 1-(N-heterylmethyl)silatranes
Autor: | E. N. Timofeeva, Vera V. Belyaeva, Elena F. Belogolova, Yu. I. Bolgova, Olga M. Trofimova |
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Rok vydání: | 2016 |
Předmět: | |
Zdroj: | Russian Chemical Bulletin. 65:1039-1046 |
ISSN: | 1573-9171 1066-5285 |
Popis: | Reactions of CuCl2 with 1-(N-indolylmethyl)and 1-(N-carbazolylmethyl)silatranes (L) afforded new complexes CuCl2•L. Quantum chemical calculations of these complexes and a CuII complex with 1-(N-pyrrolylmethyl)silatrane showed that the Cu atom is coordinated to both the equatorial O atom of the silatranyl group and the π-system of the ligandś heterocycle. |
Databáze: | OpenAIRE |
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