Formation, isomerization, and cyclization reactions of hydroperoxyalkyl radicals in hexadecane autoxidation at 160-190.degree.C
| Autor: | R. K. Jensen, S. Korcek, M. Zinbo |
|---|---|
| Rok vydání: | 1992 |
| Předmět: |
chemistry.chemical_classification
Autoxidation Radical technology industry and agriculture chemistry.chemical_element General Chemistry Reaction intermediate Hexadecane equipment and supplies Photochemistry complex mixtures Biochemistry Oxygen Catalysis chemistry.chemical_compound Colloid and Surface Chemistry Hydrocarbon Reaction rate constant chemistry Isomerization |
| Zdroj: | Journal of the American Chemical Society. 114:7742-7748 |
| ISSN: | 1520-5126 0002-7863 |
| DOI: | 10.1021/ja00046a021 |
| Popis: | Kinetic and mechanistic investigations of the effects of oxygen pressure on liquid-phase autoxidation reactions in hydrocarbons at elevated temperatures were carried out with hexadecane at 160-190 o C and at oxygen pressures from 4 to 120 kPa using a stirred-flow reactor |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|