Reaction of carbene of cyclohexadienone type with multiple bonds of conjugated dienes
Autor: | V. V. Ershov, B. D. Sviridov, G. A. Nikiforov |
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Rok vydání: | 1974 |
Předmět: | |
Zdroj: | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 23:339-342 |
ISSN: | 1573-9171 0568-5230 |
DOI: | 10.1007/bf00924683 |
Popis: | 1. The 1,2-addition products are formed initially when the cyclohexadienone carbene is reacted with the multiple bonds of conjugated dienes, which are isomerized under the conditions for the thermolysis of the quinone diazide, but are stable under photolysis conditions at 5–7°. 2. The rate of the thermal isomerization of the 1,2-addition products was studied. |
Databáze: | OpenAIRE |
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