Autor: A. L. Karpei, A. I. Akimov, G. K. Savchuk
Rok vydání: 2000
Předmět:
Zdroj: Journal of Applied Spectroscopy. 67:976-980
ISSN: 0021-9037
DOI: 10.1023/a:1004168320640
Popis: We have investigated the IR reflection spectra of ferroelectric ceramics based on solid solutions of lead zirconate-titanate with a rhombohedral structure obtained by high-pressure cold precompaction. In the 55–65-cm−1 frequency range, we have revealed by experiment that the “soft” ferroelectric-active mode for the ceramics compacted by a higher pressure under the conditions of cold compaction is shifted into the region of lower frequencies. For the ceramics precompacted at various pressures, we have determined the frequencies of longitudinal and transverse phonons and calculated the frequency dependences of the imaginary and real parts of the dielectric constant.
Databáze: OpenAIRE