New insights into the mechanical and self-healing properties of polymers cross-linked by Fe(iii)-2,6-pyridinedicarboxamide coordination complexes

Autor: Cheng-Hui Li, Jian-Cheng Lai, Ke-Yu Zeng, Sheng-Ran Mo, Jing-Lin Zuo, Da-Peng Wang
Rok vydání: 2019
Předmět:
Zdroj: Polymer Chemistry. 10:362-371
ISSN: 1759-9962
1759-9954
DOI: 10.1039/c8py01233d
Popis: In order to understand the mechanical and self-healing properties of polymers cross-linked by Fe(III)-2,6-pyridinedicarboxamide (pdca) coordination complexes, herein we performed the reaction between 2,6-pyridinedicarboxamide and FeCl3 under both neutral and alkaline conditions, and studied the dynamic ligand exchange properties of the resulting model complexes. The results showed that [Fe(Hpdca)]+ exhibited a rapid ligand exchange property which was not observed for [Fe(pdca)]−. Correspondingly, polymer Fe-Hpdca-PBCA (PBCA = poly(butadiene-co-acrylonitrile)) was weak, highly stretchable and self-healable, while Fe-pdca-PBCA was strong and poorly stretchable and can only be partially healed with a prolonged time. These results deliver a clear indication of the important impact of the bond strength and dynamics of coordination complexes on the mechanical and self-healing properties of polymers. Such an understanding is helpful for further design of novel synthetic polymers which can achieve an optimal balance between the mechanical strength and self-healing performance.
Databáze: OpenAIRE