An Oxomolybdenum(V) Cluster, [Mo8O16(OCH3)8(C5H5N)4]

Autor:	K. Prout, Jurij V. Brenčič, Ljubo Golič, Barbara Modec, R. Rotar
Rok vydání:	1998
Předmět:	chemistry.chemical_compound chemistry Molybdenum Stereochemistry Pyridine Cluster (physics) chemistry.chemical_element Molecule General Medicine Crystal structure General Biochemistry Genetics and Molecular Biology Pyridine ligand
Zdroj:	Acta Crystallographica Section C Crystal Structure Communications. 54:1573-1575
ISSN:	0108-2701
DOI:	10.1107/s0108270198006106
Popis:	The structure of octa-μ-methoxo-octa-μ-oxo-octa­oxotetra­pyridine­octa­molybdenum(V), [Mo8O16(CH3O)8(C5H5N)4], consists of discrete puckered cyclic molecules, made up of eight Mo atoms which are linked together by pairs of oxo bridges and pairs of bridging methoxy groups. It may also be regarded as a linkage of four [Mo2O4]2+ units, whose two Mo centres differ in their coordination by the pyridine ligand. Short Mo—Mo distances, 2.570 (1) A, alternate with longer Mo⋯Mo contacts, 3.435 (1) A.
Databáze:	OpenAIRE
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