ESR studies of some oxotetrahalo complexes of vanadium(IV) and molybdenum(V)

Autor:	K. K. Sunil, M. T. Rogers
Rok vydání:	1981
Předmět:	Inorganic chemistry Analytical chemistry chemistry.chemical_element Vanadium Halide Resonance (chemistry) Spectral line law.invention Inorganic Chemistry chemistry Molybdenum law Molecule Molecular orbital Physical and Theoretical Chemistry Electron paramagnetic resonance
Zdroj:	Inorganic Chemistry. 20:3283-3287
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic50224a028
Popis:	ESR spectra of (VOF/sub 4/)/sup 2 -/ and (MoOF/sub 4/)/sup -/ have been studied in single crystals of (NH/sub 4/)/sub 2/SbF/sub 5/ and spectra of (MoOCl/sub 4/)/sup -/ in single crystals of (NH/sub 4/)/sub 2/SbCl/sub 5/. The spin-Hamiltonian parameters of these pentacoordinated complexes have been obtained and compared with those for the corresponding hexacoordinated species. Molecular orbital parameters for the penta- and hexacoordinated species obtained from experimental g- and A-tensor components have been compared with values calculated by the MS-SCF-X..cap alpha.. method.
Databáze:	OpenAIRE
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