Phase Modulation in APT Spectra for ABX Patterns

Autor: T.T Nakashima, Ronald G. Cavell, R. E. D. McClung, Glen Bigam, C. M. Angelov
Rok vydání: 1997
Předmět:
Zdroj: Magnetic Resonance in Chemistry. 35:502-504
ISSN: 1097-458X
0749-1581
DOI: 10.1002/(sici)1097-458x(199708)35:8<502::aid-omr118>3.0.co;2-7
Popis: Anomalous APT spectra are reported for an organophosphorus compound containing methylene 13C nuclei coupled to two 31P nuclei. Strong coupling effects in these ABX spin systems are shown to account for the anomalous phases and intensities of the APT spectra by density matrix simulations. © 1997 John Wiley & Sons, Ltd.
Databáze: OpenAIRE