The influence of aromatic compounds on the Rh-containing structured catalyst performance in steam and autothermal reforming of diesel fuel
| Autor: | M. V. Shashkov, V.A. Shilov, V.N. Rogozhnikov, D.I. Potemkin, Pavel V. Snytnikov, V.D. Belyaev, Vladimir A. Sobyanin |
|---|---|
| Rok vydání: | 2022 |
| Předmět: |
chemistry.chemical_classification
Materials science Methane reformer Renewable Energy Sustainability and the Environment Energy Engineering and Power Technology o-Xylene Condensed Matter Physics Catalysis Reaction rate Steam reforming chemistry.chemical_compound Diesel fuel Fuel Technology Hydrocarbon chemistry Chemical engineering Naphthalene |
| Zdroj: | International Journal of Hydrogen Energy. 47:11316-11325 |
| ISSN: | 0360-3199 |
| Popis: | The detailed experimental studies of the autothermal and steam reforming of model mixtures simulating the composition of commercial diesel fuel were carried out over Rh/Ce0.75Zr0.25O2-δ-ƞ-Al2O3/FeCrAl wire mesh honeycomb catalytic modules. The components of the diesel surrogates were n-hexadecane, o-xylene, and naphthalene as model compounds of aliphatics, mono-aromatics and diaromatics, respectively. It was shown that low reaction rate of diaromatics steam reforming facilitated increasing concentration of C1–C5 hydrocarbon by-products (primarily ethylene) in the gas phase, as well as formation of polyaromatic compounds by concurrent condensation reaction. These undesirable processes were responsible for increasing catalyst coking. Monoaromatic constituents hadn't any significant effect on the progress of undesirable side-reactions during autothermal and steam reforming of diesel surrogates. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect