Palladium-Indium-Indium(III) Chloride-Mediated Allyl Cross-Coupling Reactions Using Allyl Acetates

Autor:	Eunkyong Shim, Dong Seomoon, Hyunseok Kim, Phil Ho Lee, Hyun Pyo Kim, Seokju Lee, Miae Lee, Madabhushi Sridhar, Misook Kim, Sundae Kim, Kooyeon Lee
Rok vydání:	2004
Předmět:	chemistry.chemical_element General Chemistry Photochemistry Coupling reaction Transmetalation chemistry.chemical_compound chemistry Nucleophile Indium-mediated allylation Allyl acetate Polymer chemistry Indium(III) chloride Indium Palladium
Zdroj:	Advanced Synthesis & Catalysis. 346:1641-1645
ISSN:	1615-4150
DOI:	10.1002/adsc.200404125
Popis:	Allylindiums in situ generated by reductive transmetalation of π-allylpalladium(II) complexes, obtained from allyl acetates and palladium(0) catalyst, with indium and indium(III) chloride are effective nucleophilic cross-coupling partners in Pd-catalyzed allyl cross-coupling reactions with a variety of electrophilic cross-coupling partners.
Databáze:	OpenAIRE
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