ChemInform Abstract: Rhodium-Catalyzed and Zinc(II) Triflate Promoted Asymmetric Hydrogenation of Tetrasubstituted α,β-Unsaturated Ketones

Autor:	Michael O. Frederick, Dana L. T. Laird, Scott A. May, Joel R. Calvin, Jacob R. Remacle
Rok vydání:	2012
Předmět:	Chemistry mental disorders Asymmetric hydrogenation chemistry.chemical_element Organic chemistry Noyori asymmetric hydrogenation Epimer General Medicine Zinc Trifluoromethanesulfonate Medicinal chemistry Rhodium Catalysis
Zdroj:	ChemInform. 43
ISSN:	0931-7597
DOI:	10.1002/chin.201226033
Popis:	A key feature is the use of catalytic zinc triflate, which significantly improves turnover frequency and suppresses epimerization in the α-position of the products.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::9529b5b6ddb651a9f10f2082079a1dc4 https://doi.org/10.1002/chin.201226033 Zobrazit plný text záznamu Plný text