X-ray diffraction studies oncis-[Ru(bpy)2(PMe3)Cl+][ClO4 −] andcis-[Ru(bpy)2{PMe2(o-tol)}Cl+][ClO4 −]; two ordered structures in thecis-bis(bipyridyl)chloro(phosphine)-ruthenium(II) series

Autor:	Melvyn Rowen Churchill, My Hang V. Huynh, Lynn M. Krajkowski, Kenneth J. Takeuchi
Rok vydání:	1997
Předmět:	Hydrogen bond Trimethylphosphine chemistry.chemical_element General Chemistry Crystal structure Condensed Matter Physics Ruthenium Bond length chemistry.chemical_compound Crystallography chemistry X-ray crystallography Organometallic chemistry Phosphine
Zdroj:	Journal of Chemical Crystallography. 27:589-597
ISSN:	1572-8854 1074-1542
DOI:	10.1007/bf02576457
Popis:	The complexcis-[Ru(bpy)2(PMe3)Cl+][ClO4 −] crystallizes in space group P21/c andcis-[Ru(bpy)2{PMe2(o-tol)]Cl+][ClO4 −] crystallizes in space group $$P\bar 1$$ ; each is present as a racemate and neither structure suffers from disorder. The Ru−PMe2(o-tol) bond length of 2.324(2)A is slightly longer than the simple Ru−PMe3 bond length of 2.310(2) A.
Databáze:	OpenAIRE
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