Diastereoselective α-iodination reaction of 4-alkenylamide having a β-chiral center
Autor: | Takeo Taguchi, Osamu Kitagawa, Tokushi Hanano, Masahiro Okada |
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Rok vydání: | 1997 |
Předmět: | |
Zdroj: | Tetrahedron. 53:6825-6834 |
ISSN: | 0040-4020 |
DOI: | 10.1016/s0040-4020(97)00382-7 |
Popis: | α-Iodination reaction of 4-alkenylamide with a β-chiral center proceeds with high diastereoselectivity to give syn α-iodoalkenamide through the formation of cyclic ketene N , O -acetal and subsequent α-iodination from the opposite side of a β-substituent. |
Databáze: | OpenAIRE |
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