Diastereoselective α-iodination reaction of 4-alkenylamide having a β-chiral center

Autor: Takeo Taguchi, Osamu Kitagawa, Tokushi Hanano, Masahiro Okada
Rok vydání: 1997
Předmět:
Zdroj: Tetrahedron. 53:6825-6834
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(97)00382-7
Popis: α-Iodination reaction of 4-alkenylamide with a β-chiral center proceeds with high diastereoselectivity to give syn α-iodoalkenamide through the formation of cyclic ketene N , O -acetal and subsequent α-iodination from the opposite side of a β-substituent.
Databáze: OpenAIRE